Mayuri Kurotsuchi Captain of the 12th Division in the Gotei 13
Sajin Komamura Captain of the 7th Division of the Gotei 13
Kenpachi Zaraki Bleach Gallery
Kenpachi Zaraki (更木 剣八, Zaraki Kenpachi) is the Captain of the Eleventh Division within the Gotei 13.
Soifon Commander Special Force
Soifon (砕蜂, Suìfēng in the Pinyin transliteration of Mandarin Chinese, often incorrectly romanized as Soi Fong) is the Commander-in-chief of the Special Forces and the captain of the 2nd Division in the Gotei 13(wikia)
Kaname Tōsen Captain of 9th Division
Kaname Tōsen (東仙 要, Tōsen Kaname) was originally captain of the 9th Division of the Gotei 13, but has since left Soul Society for other goals, currently being a Commander in Sōsuke Aizen's Army of Arrancar.(wikia)
Bleach Nnoitra Jiruga
Nnoitra Jiruga (ノイトラ・ジルガ, Noitora Jiruga) was the quinta (5th) Espada in Sōsuke Aizen's Army.
Stark Bleach Anime
Stark (スターク, Sutāku) is an Arrancar and the primera (1st) Espada in Sōsuke Aizen's army, making him the most powerful Arrancar or Hollow under Aizen's command. (wikia)